不但...而且 means "not only...but also" - emphasizes that something exceeds expectations.
She is not only beautiful, but also smart.
Second point (而且) should be stronger or more impressive than the first.
Second point should escalate
- 不但好看，而且便宜 (not only looks good, but cheap too)
Same subject: 不但 after subject
- 他不但會說，而且說得好
Variants: 不僅, 不光
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